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Home > Products > Heterocyclic
4,4'-Di-tert-butyl-2,2'-bipyridine CAS NO: 72914-19-3

4,4'-Di-tert-butyl-2,2'-bipyridine CAS NO: 72914-19-3

Name:4,4'-Di-tert-butyl-2,2'-bipyridine
CAS: 72914-19-3
MF: C18H24N2
MW: 268.40
MP: 159-161?C(lit.)
BP:395.4¡À42.0 ¡ãC(Predicted)
Density:0.977

Description of 4,4'-Di-tert-butyl-2,2'-bipyridine CAS NO: 72914-19-3

 

Name: 

4,4'-Di-tert-butyl-2,2'-bipyridine

 

Other name:

4,4'-di-tBu-2,2'-bipyridine;

4,4'-Bis(tert-butyl)-2,2'-bipyridine;

4,4'-di-tert-butyl-2,2'-dipyridyl;

4,4'-Di-tert-butyl-[2,2']bipyridinyl;

BBBPY; 4,4'-di-tert-butyl-bpy;

4,4'-Bis(t-butyl)-2,2'-bipyridine;

4,4'-tBu2bpy;   4,4'-dtbipy;

4,4'-Bis(2-methyl-2-propanyl)-2,2'-bipyridine;

4,4'-Di-t-butyl-2,2'-bipyridyl;

2,2'-Bipyridine, 4,4'-bis(1,1-dimethylethyl)-;

 

CAS: 72914-19-3

MF: C18H24N2

MW: 268.40

MP: 159-161ºC(lit.)

BP:395.4±42.0 °C(Predicted)
Density:0.977
Storage:Inert atmosphere,Room Temperature

Appearance: White powder

Purity: 97% min

Package: 25g, 100g, 500g, bulk package 

62

4,4'-Di-tert-butyl-2,2'-bipyridine is a maleate salt that is used in organic chemistry as a proton acceptor and donor.

4,4'-Di-tert-butyl-2,2'-bipyridine is a bipyridyl ligand that has been synthesized and characterized in various studies. It is a derivative of 2,2'-bipyridine with tert-butyl groups attached at the 4 and 4' positions, which increases its solubility and modifies its electronic properties. This ligand is particularly interesting due to its potential applications in coordination chemistry and materials science, such as in the formation of metal complexes with diverse chemical and physical properties

 

Application of 4,4'-Di-tert-butyl-2,2'-bipyridine CAS NO: 72914-19-3

1.Catalytic Activity in Carbon Dioxide Reduction
4,4'-Di-tert-butyl-2,2'-bipyridine has been identified as a significant improvement in catalysts for the reduction of carbon dioxide to carbon monoxide.

2.Synthesis of Bipyridyl Ligands
A ligand-free synthesis method for 4,4'-Di-tert-butyl-2,2'-bipyridine has been developed, utilizing nickel-catalysis.

3.Role in Molybdenum Complexes
4,4'-Di-tert-butyl-2,2'-bipyridine plays a role in the formation of molybdenum complexes. These complexes have applications in the epoxidation of olefins and are instrumental in creating hybrid materials with unique structural and chemical properties

4.Photophysical Properties in Ruthenium Complexes
This compound is integral in the synthesis of poly(bipyridine)ruthenium complexes, used as building blocks in dye-sensitized solar cells. Its role in tuning the excited-state properties of these complexes has significant implications in developing efficient solar cells


5.Application in Platinum and Rhenium Complexes
4,4'-Di-tert-butyl-2,2'-bipyridine is utilized in platinum and rhenium complexes for various applications, including exploring their photophysical and excited-state properties, which are relevant in fields like organic light emitting diodes (OLEDs) and luminescent materials


Future Directions
The compound has potential applications in various fields due to its ability to act as a ligand in chemical reactions . It can be used in the synthesis of oxidovanadium (IV) complex, which is used as a catalyst for the epoxidation of cyclooctene . It also enables nickel-catalyzed cross-electrophile couplings of diverse aryl and alkyl halides , suggesting its potential use in the development of new synthetic methodologies.

 

 

 

4,4'-Di-tert-butyl-2,2'-bipyridine CAS NO: 72914-19-3

 

4,4'-Di-tert-butyl-2,2'-bipyridine CAS NO: 72914-19-3

 

 

4,4'-Di-tert-butyl-2,2'-bipyridine CAS NO: 72914-19-3

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