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Name: Cab-Ph-TRZ
CAS No.: 440354-93-8
MF: C33H22N4
MW: 474.55 g/mol
Purity: 97% Min.
Appearance: Off-white powder/crystals
Application: OLED/OFET/OPV Materials
Name: Cab-Ph-TRZ
Full name:
9-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9H -carbazole.
Synonyms: CzPhTRz, CzTRZ, Cz-Ph-TRZ, PhCzTRZ
CAS No.: 440354-93-8
MF: C33H22N4
MW: 474.55 g/mol
Absorption:λmax 262, 356 nm in DCM
Fluorescence:λmax 467 nm in DCM
HOMO/LUMO: HOMO 5.9 eV, LUMO 2.98 eV [1]
MP: TGA: 300 °C (0.5% weight loss)
Purity: 97% Min.
Appearance: Off-white powder/crystals
Application: OLED/OFET/OPV Materials
Storage Condition: Store in a cool, dry place. Keep the container closed when not in use.
Cab-Ph-TRZ is typically used as a phosphorescent host material for green and red light-emitting diodes. Compared to CBP - 4,4′-Bis(N-carbazolyl)-1,1′-biphenyl (CAS: 58328-31-7) as a host material, Cab-Ph-TRZ shows higher power efficiencies with lower driving voltage, thanks to its bipolar nature.
Literature and Reviews
Tailoring electronic structure of organic host for high-performance phosphorescent organic light-emitting diodes, J. Xiao et al., Org. Electrons, 15, 2763–2768 (2014); DIO: 10.1016/j.orgel.2014.08.006.
Operational lifetimes of organic light-emitting diodes dominated by Förster resonance energy transfer, H. Fukagawa et al., Sci. Reports, 7:1735 (2017); DOI:10.1038/s41598-017-02033-3.
A New Design Strategy for Efficient Thermally Activated Delayed Fluorescence Organic Emitters: From Twisted to Planar Structures, X-K. Chen et al., Adv. Mater., 29, 1702767 (2017); DOI: 10.1002/adma.201702767.
Turn on of sky-blue thermally activated delayed fluorescence and circularly polarized luminescence (CPL) via increased torsion by a bulky carbazolophane donor, N. Sharma et al., Chem. Sci., 10, 6689-6696 (2019); DOI: 10.1039/C9SC01821B.
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