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Name: Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct

Synonyms: 

笔诲2(诲产补)3·颁贬颁濒3;

Dipalladium-tris(dibenzylideneacetone)chloroform complex;

1,4-Pentadien-3-one, 1,5-diphenyl-, (1E,4E)-, compd. with trichloromethane, palladium salt (3:1:2);

1,2,4,5-Pentanetetrayl, 3-oxo-1,5-diphenyl-, compd. with trichloromethane, palladium salt (3:1:2).

CAS No.: 52522-40-4   

EINECS: 610-856-2

MF: C52H43Cl3O3Pd2

MW: 1035.1g/mol

MP: 131-135℃(lit.)

BP: 400.7℃ at 760 mmHg

FP: 176.2℃

Purity: 97% Min.

Palladium (Pd): ≥20.5% 

Appearance: Purple to black crystalline powder

Solubility: Soluble in organic solvents. Insoluble in water. 

Application: 

Used to compose the catalytic system for the preparation of homoallylpalladium complexes.

Used as palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.

Used as a catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.

Used as cyclization catalyst.

Used as a catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.

Used as a catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.

Package: 1g/5g/10g/50g/100g or as your special request.

Storage Conditions: Sealed and stored in the refrigerator(0-6℃).

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